Publications 2000-2009

  1. G. Hadt, V. N. Nemykin, J. G. Olsen, P. Basu, “Comparative Calculation of EPR Spectral Parameters in [MoVOX4], [MoVOX5]2-, and [MoVOX4(H2O)] complexes,” Physical Chemistry Chemical Physics, 11, 10377-10384 (2009).
  2. W. Kail, C.G. Young, M.E. Johnson, P. Basu, “Understanding Oxotransferase Reactivity in a Model System Using Singular Value Decomposition Analysis,” ACS Symposium Series, 1012 (Bioinorganic Chemistry), Baldwin, M.; Long, E. Eds. 199-217 (2009).
  3. Perera, P. Basu, “Synthesis, characterization and structure of a Low coordinate Desoxomolybdenum cluster stabilized by a Dithione Ligand,” Dalton Trans., 5023-5028 (2009).
  4. Basu, V.N. Nemykin, R.S. Sengar, “Substituent Effect on Oxygen Atom Transfer Reactivity from Oxomolybdenum Centers– Synthesis, Structure, Electrochemistry, and Mechanism,” Inorg. Chem., 48, 6303-6313 (2009).
  5. Basu, “Arsenic”, Mol. Nutr. Food Res., 53, 529-530 (2009).
  6. Richey, P. Chovanec, S. E Hoeft, R. S. Oremland, P. Basu, J.F Stolz, “Respiratory Arsenate Reductase as a Bidirectional Enzyme,” Biochem. Biophys. Res. Commun., 382, 298-302 (2009).
  7. Marbella,# B. Serli-Mitasev, P. Basu, “Development of a new fluorescent Pb2+ sensor” Ang. Chem. Int. Ed. Engl. 48, 3996-3998 (2009).
  8. Fisher, A. M. Dawson, G. Polshnya, J. Lisak, B. Crable, E. Perera, M. Ranganathan, M. Thangavelu, P. Basu, and J. F. Stolz, “Transformation of inorganic and organic arsenic by Clostridium oremlandii sp. nov. strain OhILAs,” In “Incredible Anaerobes: From Physiology to Genomics to Fuels” J. Wiegel, R. Maier and M. Adams (Eds.) Ann. NY Acad. Sci., 1125 (Incredible Anaerobes), 230-241, (2008).
  9. S. Sengar, J. J. Miller, # and P. Basu, “Design, Syntheses, and Characterization of Dioxo-molybdenum(VI) Complexes With Thiolate Ligands: Effects of Intraligand NH•••S Hydrogen Bonding,” Dalton Trans., 2569-2577. (2008).
  10. Basu, R. N. Ghosh, L. E. Grove, L. Klei, A. Barchowsky, “Angiogenic Potential of 3-Nitro-4-Hydroxy Benzene Arsonic Acid (Roxarsone)” Environ. Health Persp., 116(4), 520-523, (2008).
  11. R. Sengar, V. N. Nemykin and P. Basu, “Synthesis, Electrochemistry, Geometric and Electronic Structure of Oxo-Molybdenum Compounds Involved in an Oxygen Atom Transferring System,” J. Inorg. Biochem., 102, 748-756 (2008).
  12. F. Stolz, E. Perera, B. Kilonzo,# B. Kail, B. Crable, E. Fisher, M. Ranganathan, L. Wormer, and P. Basu “Biotransformation of 3-Nitro-4-hydroxybenzene arsonic acid (Roxarsone) and Release of Inorganic Arsenic by Clostridium species,” Environ. Sci. Technol. 41, 818-823 (2007).
  13. S. Sengar and P. Basu, “Design, Syntheses, and Characterization of a Sterically Encumbered Dioxo Molybdenum (VI) Core,” Inorg. Chim. Acta., 360, 2092–2099 (2007)
  14. N. Nemykin, J. G. Olsen,# E. Perera, and P. Basu, “Synthesis, Characterization, and Crystal Structure of the (Me2Pipdt)Mo(CO)4 Complex (Me2Pipdt = N,N’-Dimehylpiperazine-2,3-dithione). A DFT, TDDFT, and TDDFT-PCM Study on Its Electronic Structure, Excited States, and Solvatochromism,” Inorg. Chem., 45, 3557-3568 (2006).
  15. F. Stolz, P. Basu, J. M. Santini, and R. S. Oremland, “Arsenic and Selenium in Microbial Metabolism,” Ann. Rev. Microbiol., 60, 107-130 (2006).
  16. W. Kail, L. M. Pérez, S. D. Zarić, A. Millar, C. G. Young, M. B. Hall, and P. Basu, “Mechanistic Investigation of the Oxygen Atom Transfer Reactivity of Dioxo-Molybdenum(VI) Complexes,” Chem. Eur. J. 12, 7501-7509 (2006).
  17. W. Kail, P. Basu, “Solvent Effects in the Geometric Reorganization of an oxo-molybdenum(V) system,” Dalton Trans., 1419 – 1423 (2006).
  18. L. McNaughton, S. Mondal, V. N. Nemykin, P. Basu, and M. L. Kirk, “Oxomolybdenum Tetrathiolates with Sterically Encumbering Ligands: Modeling the Effect of a Protein Matrix on Electronic Structure and Reduction Potentials,” Inorg. Chem., 44, 8216-8222, (2005).
  19. N. Nemykin and P. Basu, “Oxygen Atom Transfer Reactivity from a dioxo-Mo(VI) Complex to Tertiary Phosphine: Synthesis, Characterization and Structure of Phosphoryl Intermediate Complexes,” Inorg. Chem., 44, 7494-7502 (2005).
  20. N. Nemykin and P. Basu, “Energy Dependent Electrospray Ionisation mass spectrometric studies of mononuclear metal carbonyls,” Inorganica Chimica Acta, 358, 2876–2882 (2005).
  21. J. Millar, C. J. Doonan, P. D. Smith, V. N. Nemykin, P. Basu and C. G. Young, “Oxygen Atom Transfer in Models for Molybdenum Enzymes: Isolation and Spectroscopic and Structural Characterization of Intermediates in the Transfer of Oxygen from Mo(VI) to P(III),” Chem. Eur. J. 11, 3255-3267, (2005).
  22. J. Rogers, P. Basu, “Factor Regulating Macrophage Endocytosis of Nanoparticles: Implications for Targeted Magnetic Resonance Plaque Imaging,” Atherosclerosis, 178, 67-73 (2005).
  23. T. Hoffman, S. Einwaechter, B. S. Chohan, P. Basu, and C. J. Carrano, “Isomerization and Oxygen Atom Transfer Reactivity in oxo-Mo Complexes of Relevance to Molybdoenzymes,” Inorg. Chem., 43, 7573-7575 (2004).
  24. N. Nemykin and P. Basu, “A bifurcated pathway of oxygen transfer reactions from a mono-oxo molybdenum(VI) complex under electrospray ionisation mass spectrometric conditions,” Dalton Trans., 1928-1933 (2004).
  25. N. Nemykin, J. Laskin, and P. Basu, “Isolation, Characterization of an Intermediate in an Oxygen Atom Transfer Reaction and the Determination of the Bond Dissociation Energy,” J. Am. Chem. Soc., 126, 8604-8605 (2004).
  26. Basu, “Geometric perturbation of electronic structure of discrete molybdenum(V) cores and the reduction potential,” CHEMTRACTS: Inorganic Chemistry, 17, 12-23 (2004).
  27. Basu and J. F. Stolz Book Review: “Functional Genomics Series (Volume III): Frontiers in Computation Genomics,” Ed: Michael Y. Galperin and Eugene V. Koonin, ChemBioChem, (2004), 5, 546-547.
  28. Basu, V. N. Nemykin, R. Sengar, “Synthesis, spectroscopy, and redox chemistry of encapsulated oxo-Mo(V) centers: implications for pyranopterin-containing molybdoenzymes,” Inorg. Chem., 42, 7489-7501 (2003).
  29. J. Carrano, B. S. Chohan, B. S. Hammes, B. Kail, V. N. Nemykin and P. Basu, “Donor Atom Dependent Geometric Isomers in Mononuclear Oxo-Molybdenum (V) Complexes: Implications for Coordinated Endogenous Ligation in Molybdoenzymes,” Inorg. Chem., 42, 5999-6007 (2003).
  30. Afkar, J. Lisak, C. Saltikov, P. Basu, R.S. Oremland, J.F. Stolz, “The respiratory arsenate reductase from a haloalkaliphilic bacterium Bacillus selenitireducens Strain MLS10,” FEMS Microbiol Lett., 226, 107-112 (2003).
  31. S. Sengar, V.N. Nemykin, P. Basu, “Electronic Properties of para-Substituted Thiophenols and Disulfides from 13C NMR Spectroscopy and ab initio Calculations: Relations to the Hammett Parameters and Atomic Charges,” New J. Chem., 27, 1115-1123 (2003).
  32. N. Nemykin and P. Basu, “Comparative theoretical investigation of the vertical excitation energies and the electronic structure of [MoVOCl4]: Influence of basis set and geometry”, Inorg. Chem., 42, 4046-4056 (2003).
  33. P Basu, J. F. Stolz and M. T. Smith#, “A coordination chemist’s view of the active sites of mononuclear molybdenum enzymes,” Current Sci. 84, 1412-1418 (2003).
  34. F. Stolz, P. Basu and R.S. Oremland, “The Microbial Transformation of Elements: The Case of Arsenic and Selenium,” Int. Microbiol, 5, 201-207 (2002).
  35. F. Stolz, P. Basu, “Evolution of Nitrate Reductase: Molecular and Structural Variations on a Common Function,” ChemBioChem, 3, 198-206, (2002).
  36. Kail, V. N. Nemykin, S. R. Davie,# C. J. Carrano, B.S. Hammes, P. Basu, “Synthesis, Characterization, Electrochemistry, Electronic Structure, and Isomerization in Mononuclear oxo-Molybdenum(V) Complexes: The Serine Gate Hypothesis in the Function of DMSO Reductases,” Inorg. Chem, 41, 1281-1291, (2002).
  37. N. Nemykin, S. R. Davie,# S. Mondal, N. Rubie, M. L. Kirk, A. Somogyi, P. Basu, An Analogue System Displaying all the Important Processes of the Catalytic Cycles Involving Monooxo-Molybdenum(VI) and Desoxo-Molybdenum(IV) Centers,” J. Am. Chem. Soc., 124, 756-757 (2002).
  38. R. Davie,# N. Rubie, B.S. Hammes, C.J. Carrano, M.L.Kirk, P.Basu, “Stereochemical control of reduction potential in oxomolybdenum centers: implications to the serine coordination in DMSO reductase,” Inorg. Chem. 40, 2632-2633 (2001).
  39. Mondal, P. Basu, “Dendrimer Encapsulation of [MoVOS4] Cores: Implications for the DMSO Reductase Family of Enzymes,” Inorg. Chem., 40, 192-193 (2001).
  40. D. Smith, A. J. Millar, C.G. Young, A. Ghosh, P. Basu, “Detection, Isolation and Characterization of Intermediates in Oxygen Atom Transfer Reactions in Molybdoenzyme Model Systems,” J. Am. Chem. Soc., 122, 9298-9299 (2000).